1. Go to the "Settings" tab, then down into "Accessory Settings", then down into "Manage Bluetooth Devices".
2. Follow the onscreen instructions and let the PS3 scan for your headset. When your headset is found, follow the prompts and enter a pass key (default is usually 0000). The pairing should now be complete.
Go through your headset's manual to find out how to put it into pairing mode as well.
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