Hi and Welcome to TSF
These links should set you on your way
Or you can try the Backup Wizard
You can transfer your email messages manually, using the Import / Export commands of Outlook Express, but transferring other settings such as accounts, rules, signatures, and identities is a very complicated process that requires advanced technical skills. Outlook Express Backup Wizard makes it very simple to transfer your data by following these easy steps:
1. Backup your Outlook Express with Outlook Express Backup Wizard.
2. Copy the resulting backup file to the target computer via LAN, CDR, or removable drive.
3. Restore the backup file to Outlook Express on the second computer. To do this, run the wizard, choose the Restore option, and select your backup file.